The LAST MINUTE corpus comprises multimodal recordings (e.g. video, audio, transcripts) from WOZ interactions in a mundane planning task (Rösner et al., 2011). It is one of the largest corpora with naturalistic data currently available. In this paper we report about first results from attempts to automatically and manually analyze the different modes with respect to emotions and affects exhibited by the subjects. We describe and discuss difficulties encountered due to the strong contrast between the naturalistic recordings and traditional databases with acted emotions.