Large language models (LLM’s) have been widely used for several applications such as question answering, text classification and clustering. While the preliminary results across the aforementioned tasks looks promising, recent work has dived deep into LLM’s performing poorly for complex Named Entity Recognition (NER) tasks in comparison to fine-tuned pre-trained language models (PLM’s). To enhance wider adoption of LLM’s, our paper investigates the robustness of such LLM NER models and its instruction fine-tuned variants to adversarial attacks. In particular, we propose a novel attack which relies on disentanglement and word attribution techniques where the former aids in learning an embedding capturing both entity and non-entity influences separately, and the latter aids in identifying important words across both components. This is in stark contrast to most techniques which primarily leverage non-entity words for perturbations limiting the space being explored to synthesize effective adversarial examples. Adversarial training results based on our method improves the F1 score over original LLM NER model by 8% and 18% on CoNLL-2003 and Ontonotes 5.0 datasets respectively.