Document-level relation extraction (DocRE) attracts more research interest recently. While models achieve consistent performance gains in DocRE, their underlying decision rules are still understudied: Do they make the right predictions according to rationales? In this paper, we take the first step toward answering this question and then introduce a new perspective on comprehensively evaluating a model. Specifically, we first conduct annotations to provide the rationales considered by humans in DocRE. Then, we conduct investigations and discover the fact that: In contrast to humans, the representative state-of-the-art (SOTA) models in DocRE exhibit different reasoning processes. Through our proposed RE-specific attacks, we next demonstrate that the significant discrepancy in decision rules between models and humans severely damages the robustness of models. After that, we introduce mean average precision (MAP) to evaluate the understanding and reasoning capabilities of models. According to the extensive experimental results, we finally appeal to future work to consider evaluating the understanding ability of models because the improved ability renders models more trustworthy and robust to be deployed in real-world scenarios. We make our annotations and code publicly available.