We report on the ongoing development of IDION, a web resource of richly documented multiword expressions (MWEs) of Modern Greek addressed to the human user and to NLP. IDION contains about 2000 verb MWEs (VMWEs) of which about 850 are fully documented as regards their syntactic flexibility, their semantics and the semantic relations with other VMWEs. Sets of synonymous MWEs are defined in a bottom-up manner revealing the conceptual organization of the MG VMWE domain.