Iterative preference optimization is essential for aligning Large Language Models on mathematical reasoning tasks, yet its efficiency is often throttled by signal scarcity: as the model improves, static problem sets become increasingly mismatched to the model’s evolving competence, producing rollouts that are either too easy or too hard and therefore non-informative, which leads to a scarcity of valid preference pairs. We propose DIAG, a Diagnostic Iterative Alignment and Generation framework that adaptively reshapes the practice distribution to increase informative supervision and focus training near the student’s current competence boundary. DIAG consists of two phases: (1) diagnosing valid preference-pair yield to calibrate the exploration-exploitation trade-off and allocate topic quotas via an Empirical Bayes shrinkage estimator, thereby prioritizing high-yield concepts; and (2) generating targeted practice, where a teacher synthesizes variants from the student’s failure traces. We further provide a theoretical view interpreting DIAG as a teacher-mediated approximation to KL-regularized reweighting of the practice distribution toward the student’s competence boundary, where valid preference-pair yield is maximized. Experiments show that DIAG boosts yield across iterations and delivers stronger reasoning performance under an iso-effective training budget, demonstrating that it can distill more informative preference supervision for mathematical reasoning.

Iterative Direct Preference Optimization (DPO) has emerged as a widely used paradigm for aligning Large Language Models on reasoning tasks. Existing approaches typically rely on Best-of-N sampling (N≥8) to mine positive trajectories from the distribution tail. In this work, we show that in mathematical reasoning, increasing N yields diminishing returns while increasing verifier-induced false-positive risk and the distribution shift required for policy updates. To address this, we introduce PACE (Proximal Alignment via Corrective Exploration), a generation-based corrective framework that replaces exhaustive mining with low-budget exploration (2≤ N≤3). Rather than searching for increasingly rare positive samples, PACE synthesizes high-fidelity preference pairs from failed explorations through corrective hindsight refinement and verification-guided filtering. Empirically, PACE matches or exceeds the performance of DPO-R1 (N=16) while using about 1/5 of the compute, and remains robust under 20% label corruption, where high-N baselines exhibit substantially higher noise exploitation.