In this paper we present two large-scale verbal lexicons, AnCora-Verb-Ca for Catalan and AnCora-Verb-Es for Spanish, which are the basis for the semantic annotation with arguments and thematic roles of AnCora corpora. In AnCora-Verb lexicons, the mapping between syntactic functions, arguments and thematic roles of each verbal predicate it is established taking into account the verbal semantic class and the diatheses alternations in which the predicate can participate. Each verbal predicate is related to one or more semantic classes basically differentiated according to the four event classes -accomplishments, achievements, states and activities-, and on the diatheses alternations in which a verb can occur. AnCora-Verb-Es contains a total of 1,965 different verbs corresponding to 3,671 senses and AnCora-Verb-Ca contains 2,151 verbs and 4,513 senses. These figures correspond to the total of 500,000 words contained in each corpus, AnCora-Ca and AnCora-Es. The lexicons and the annotated corpora constitute the richest linguistic resources of this kind freely available for Spanish and Catalan. The big amount of linguistic information contained in both resources should be of great interest for computational applications and linguistic studies. Currently, a consulting interface for these lexicons is available at (http://clic.ub.edu/ancora/).