Learning multilingual sentence embeddings is a fundamental task in natural language processing. Recent trends in learning both monolingual and multilingual sentence embeddings are mainly based on contrastive learning (CL) among an anchor, one positive, and multiple negative instances. In this work, we argue that leveraging multiple positives should be considered for multilingual sentence embeddings because (1) positives in a diverse set of languages can benefit cross-lingual learning, and (2) transitive similarity across multiple positives can provide reliable structural information for learning.In order to investigate the impact of multiple positives in CL, we propose a novel approach, named MPCL, to effectively utilize multiple positive instances to improve the learning of multilingual sentence embeddings. Experimental results on various backbone models and downstream tasks demonstrate that MPCL leads to better retrieval, semantic similarity, and classification performance compared to conventional CL. We also observe that in unseen languages, sentence embedding models trained on multiple positives show better cross-lingual transfer performance than models trained on a single positive instance.