Large Language Models (LLMs) are transforming chemical research by enabling specialized reasoning models and tool-augmented agents. Yet existing benchmarks typically evaluate reasoning or tool invocation in isolation, overlooking the dynamic interaction between internal deliberation and external execution. We present ChemEval2, a multimodal benchmark for tool-augmented chemical reasoning, containing 2,410 samples spanning fundamental principles, spectroscopic analysis, and complex reaction understanding. Built from professional textbooks and experimental data through automated generation and rigorous human annotation, ChemEval2 introduces a tool-augmented Chain-of-Thought evaluation framework that embeds tool-use checkpoints at stages where unaided language reasoning becomes unreliable. This design evaluates whether models can identify information gaps, invoke appropriate tools, and integrate tool outputs into reasoning trajectories. Across diverse text and multimodal models, we observe a process–outcome inconsistency: models can satisfy intermediate reasoning steps or execute useful tool calls yet still fail at final synthesis. These results provide evidence that coordinating computational tool use with downstream chemical reasoning remains a substantial challenge. We open-source ChemEval2 and an MCP-based suite of specialized chemical tools for reproducible.

Industrial recommendation training increasingly relies on decentralized multi-GPU infrastructure, yet sparse embedding tables remain a major bottleneck due to significant storage, lookup, and communication overhead. Most existing works typically optimize only one of these bottlenecks or are designed for parameter server architectures, making them less effective in industrial decentralized training stacks. To tackle these challenges, we propose MixEmb, a practical framework for efficient decentralized embedding training through importance-aware quantization and caching. We first design a novel importance metric, i.e., embedding score, which can distinguish the contribution of embedding vectors based on spatial heterogeneity and temporal dynamics. Guided by embedding scores, MixEmb employs mixed precision quantization and hierarchical caching at fine-grained vector level. Besides, our key finding is that quantization and caching decisions are tightly coupled. Instead of naive combination, we delicately integrate them into a unified training framework through coupled co-design. A theoretical convergence analysis is also provided for MixEmb. We implement and evaluate MixEmb in real-world training scenarios. Across three workloads, MixEmb attains up to 1.55× speedup and 3.54× compression ratio compared to state-of-the-art methods.